Manganese Oxide

Part No: RXSOL-19-6250-050

Agriculture Feed Manganous oxide MnO is used as a soil amendment, fertilizer component, and animal feed nutrient supplement

Category

Safety Data (MSDS)

Porduct Name       

Manganese  Oxide

Part Number   RXSOL-19-6250-050

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail@rxmarine.com
Website www.rxmraine.com

Component                Cas No                         Weight %    
Manganese oxide  1313-13-9 88

Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Oxidizing solids Category 2
Acute oral toxicitys Category 4
Acute Inhalation Toxicity - Dusts and Mists Category 4
Specific target organ toxicity - (repeated exposure) Category 2
Target Organs - Brain.  

 Label Elements 

Signal Word Danger
Hazard Statements May intensify fire; oxidizer May cause damage to organs through prolonged or repeated exposure Harmful if swallowed or if inhaled
Precautionary Statements
Prevention         
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Wear protective gloves/protective clothing/eye protection/face protection
Wash face, hands and any exposed skin thoroughly after handling
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Wear protective gloves/protective clothing/eye protection/face protection
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product                                    
Response Get medical attention/advice if you feel unwel
Inhalation  IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell
Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth
Fire In case of fire: Use CO2, dry chemical, or foam for extinction
Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) None identified

General Advice If symptoms persist, call a physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention
Skin Contact   Wash off immediately with plenty of water for at least 15 minutes. If skin irritationpersists,call a physician.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attentionif symptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attentionif symptoms occur.
Most important symptoms and effects  None reasonably foreseeable.
Notes to Physician Treat symptomatically

Unsuitable extinguishing media No information available
Flash Point No information available
Method  No information available
Autoignition Temperature No information available
Explosion Limits  
Upper No data available
LowerNo data available No data available
Oxidizing Properties Oxidizer
Sensitivity to Mechanical Impac          No information available
Sensitivity to Static Discharge  No information available
Specific Hazards Arising from the Chemical Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).
Hazardous Combustion Products None known
Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) andfull protective gear.

NFPA

    Health                  Flammability              Instability             Physical hazards          
        2           1               1               OX

Personal Precautions
Ensure adequate ventilation. Use personal protective equipment as required. Avoiddust
formation.Ensure adequate ventilation. Use personal protective equipment as required. Avoiddust
formation.
Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information.
Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closedcontainers for disposal. Soak up with inert absorbent material. Sweep up and shovel intosuitable containers for disposal.
Autoignition Temperature No information available

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Donot get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. Keep away from clothing and other combustible materials.
Storage.

Keep containers tightly closed in a dry, cool and well-ventilated place. Do not storenearcombustible materials. Incompatible Materials. Strong reducing agents. Combustiblematerial.

 

Component                         ACGIH TLV                                   OSHA PEL                           NIOSH IDLH                                       Mexico OEL (TWA)
Manganese(IV) oxide TWA: 0.02 mg/m3 TWA: 0.1 mg/m3 (Vacated) Ceiling: 5 mg/m3 Ceiling: 5 mg/m3

IDLH: 500 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3

TWA: 0.2 mg/m3

Personal Protective Equipment

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstationlocation. Ensure adequate ventilation, especially in confined areasAmerican Conference of Governmental Industrial Hygienists
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as describedbyOSHA's eye and face protection regulations in 29 CFR 1910.133 or EuropeanStandardEN166
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. 
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or EuropeanStandardEN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Physical state Solid
Appearance No information available
Odor No information available
Odor Threshold No information availabl
pH No information available
Melting point/freezing point -535 °C / 995 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not  Applicable
Flammability (solid,gas) No information available
Flammability or explosive limits     
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density available Vapor Density N
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water      No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula Mn O2
Molecular Weight 86.94

Reactive Hazard     Yes
Stability Stable under normal conditions. Oxidizer: Contact with combustible/organic material maycause fire.
Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Combustible material.
Incompatible Materials Strong reducing agents, Combustible material            
Hazardous Decomposition Products
None under normal use conditions
  In the event of fire: see section 5
Hazardous Reactions None under normal processing. 

Acute Toxicity

Product Information
Component Information
 
Component                          LD50 Oral                        LD50 Dermal                   LC50 Inhalation                     
Manganese(IV) oxide LD50 = 9000 mg/kg ( Rat ) Not listed LC50 > 1500 mg/m3 ( Rat ) 4 h
 
Delayed and immediate effects as well as chronic effects from short and long-term exposure
 
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as acarcinogen 
Mutagenic Effects No information available
Reproductive Effects No information avai
Developmental Effects No information available.
Teratogenicity No information available.
Stot- single exposure  None known
Stot- repeated exposu Brain
Aspiration hazard No information available
Symptoms / effects,both acute and     delayed  No information available
Endocrine Disruptor Information No information available
Mobility No information available
 
 

 

Persistence and Degradability Persistence is unlikely
Bioaccumulation/ Accumulation  
  dicates whether each agency has listed any ingredient as acarcinogen 
Mutagenic Effects No information available
Reproductive Effects No information avai
Developmental Effects No information available.
Teratogenicity No information available.
Stot- single exposure  None known

Waste Disposal Methods

Chemical waste generators must determine whether a discarded chemical is classifiedasahazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classificatio 

DOT  
UN-No UN1479
Proper Shipping
 Name
Oxidizing solid, n.o.s.
Hazard Class 5.1
Packing Group II
TDG  
UN-No UN1479
Proper Shipping Name Oxidizing solid, n.o.s
Hazard Class 5.1
Packing Group II
IATA     
UN-No UN1479
Proper Shipping Name Oxidizing solid, n.o.s
Hazard Class 5.1
Packing Group II
IMDG/IMO  
UN-No UN1479
Proper Shipping Name      Oxidizing solid, n.o.s
Hazard Class 5.1
Packing Group II

United States of America Inventory

 Component       CAS No                 TSCA            TSCA Inventory notification -

         Active-Inactive                 

TSCA - EPA Regulatory

              Flags        

Manganese(IV) oxide    1313-13-9      X              ACTIVE  

Legend

TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)

X - Listed

X - Listed '-' - Not Listed

TSCA 12(b) - Notices of Export Not applicable

Component   CAS No    DSL  NDSL  EINECS     PICCS  ENCS      ISHL       AICS      KECL    
 Manganese oxide        1313-13-9     X               
 
215-202-6    X X X X KE-23017

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

No data available

 

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

 

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.