Part No: RXSOL-19-6250-050
Agriculture Feed Manganous oxide MnO is used as a soil amendment, fertilizer component, and animal feed nutrient supplement
Safety Data (MSDS)

| Porduct Name |
Manganese Oxide |
| Part Number | RXSOL-19-6250-050 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |

| Component | Cas No | Weight % |
| Manganese oxide | 1313-13-9 | 88 |
Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
| Oxidizing solids | Category 2 |
| Acute oral toxicitys | Category 4 |
| Acute Inhalation Toxicity - Dusts and Mists | Category 4 |
| Specific target organ toxicity - (repeated exposure) | Category 2 |
| Target Organs - Brain. |
Label Elements
| Signal Word | Danger |
| Hazard Statements | May intensify fire; oxidizer May cause damage to organs through prolonged or repeated exposure Harmful if swallowed or if inhaled |
| Precautionary Statements | |
| Prevention |
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Wear protective gloves/protective clothing/eye protection/face protection
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product |
| Response | Get medical attention/advice if you feel unwel |
| Inhalation | IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell |
| Ingestion | IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth |
| Fire | In case of fire: Use CO2, dry chemical, or foam for extinction |
| Disposal | Dispose of contents/container to an approved waste disposal plant |
| Hazards not otherwise classified (HNOC) | None identified |

| General Advice | If symptoms persist, call a physician. |
| Eye Contact | Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention |
| Skin Contact | Wash off immediately with plenty of water for at least 15 minutes. If skin irritationpersists,call a physician. |
| Inhalation | Remove to fresh air. If not breathing, give artificial respiration. Get medical attentionif symptoms occur. |
| Ingestion | Clean mouth with water and drink afterwards plenty of water. Get medical attentionif symptoms occur. |
| Most important symptoms and effects | None reasonably foreseeable. |
| Notes to Physician | Treat symptomatically |

| Unsuitable extinguishing media | No information available |
| Flash Point | No information available |
| Method | No information available |
| Autoignition Temperature | No information available |
| Explosion Limits | |
| Upper | No data available |
| LowerNo data available | No data available |
| Oxidizing Properties | Oxidizer |
| Sensitivity to Mechanical Impac | No information available |
| Sensitivity to Static Discharge | No information available |
| Specific Hazards Arising from the Chemical | Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.). |
| Hazardous Combustion Products | None known |
| Protective Equipment and Precautions for Firefighters | As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) andfull protective gear. |
NFPA
| Health | Flammability | Instability | Physical hazards |
| 2 | 1 | 1 | OX |

| Personal Precautions |
Ensure adequate ventilation. Use personal protective equipment as required. Avoiddust
formation.Ensure adequate ventilation. Use personal protective equipment as required. Avoiddust
formation.
|
| Environmental Precautions | Should not be released into the environment. See Section 12 for additional Ecological Information. |
| Methods for Containment and Clean Up | Sweep up and shovel into suitable containers for disposal. Keep in suitable, closedcontainers for disposal. Soak up with inert absorbent material. Sweep up and shovel intosuitable containers for disposal. |
| Autoignition Temperature | No information available |

| Handling | Wear personal protective equipment/face protection. Ensure adequate ventilation. Donot get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. Keep away from clothing and other combustible materials. |
| Storage. |
Keep containers tightly closed in a dry, cool and well-ventilated place. Do not storenearcombustible materials. Incompatible Materials. Strong reducing agents. Combustiblematerial. |

| Component | ACGIH TLV | OSHA PEL | NIOSH IDLH | Mexico OEL (TWA) |
| Manganese(IV) oxide | TWA: 0.02 mg/m3 TWA: 0.1 mg/m3 | (Vacated) Ceiling: 5 mg/m3 Ceiling: 5 mg/m3 |
IDLH: 500 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3 |
TWA: 0.2 mg/m3 |
Personal Protective Equipment
| Engineering Measures | Ensure that eyewash stations and safety showers are close to the workstationlocation. Ensure adequate ventilation, especially in confined areasAmerican Conference of Governmental Industrial Hygienists |
| Eye/face Protection | Wear appropriate protective eyeglasses or chemical safety goggles as describedbyOSHA's eye and face protection regulations in 29 CFR 1910.133 or EuropeanStandardEN166 |
| Skin and body protection | Wear appropriate protective gloves and clothing to prevent skin exposure. |
| Respiratory Protection | Follow the OSHA respirator regulations found in 29 CFR 1910.134 or EuropeanStandardEN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. |
| Hygiene Measures | Handle in accordance with good industrial hygiene and safety practice. |

| Physical state | Solid |
| Appearance | No information available |
| Odor | No information available |
| Odor Threshold | No information availabl |
| pH | No information available |
| Melting point/freezing point | -535 °C / 995 °F |
| Boiling Point/Range | No information available |
| Flash Point | No information available |
| Evaporation Rate | Not Applicable |
| Flammability (solid,gas) | No information available |
| Flammability or explosive limits | |
| Upper | No data available |
| Lower | No data available |
| Vapor Pressure | No information available |
| Vapor Density | available Vapor Density N |
| Specific Gravity | No information available |
| Solubility | No information available |
| Partition coefficient; n-octanol/water | No data available |
| Autoignition Temperature | No information available |
| Decomposition Temperature | No information available |
| Viscosity | Not applicable |
| Molecular Formula | Mn O2 |
| Molecular Weight | 86.94 |

| Reactive Hazard | Yes |
| Stability | Stable under normal conditions. Oxidizer: Contact with combustible/organic material maycause fire. |
| Conditions to Avoid | Incompatible products. Excess heat. Avoid dust formation. Combustible material. |
| Incompatible Materials | Strong reducing agents, Combustible material |
| Hazardous Decomposition Products |
None under normal use conditions
|
| In the event of fire: see section 5 | |
| Hazardous Reactions | None under normal processing. |

Acute Toxicity
| Component | LD50 Oral | LD50 Dermal | LC50 Inhalation |
| Manganese(IV) oxide | LD50 = 9000 mg/kg ( Rat ) | Not listed | LC50 > 1500 mg/m3 ( Rat ) 4 h |
| Irritation | No information available |
| Sensitization | No information available |
| Carcinogenicity | The table below indicates whether each agency has listed any ingredient as acarcinogen |
| Mutagenic Effects | No information available |
| Reproductive Effects | No information avai |
| Developmental Effects | No information available. |
| Teratogenicity | No information available. |
| Stot- single exposure | None known |
| Stot- repeated exposu | Brain |
| Aspiration hazard | No information available |
| Symptoms / effects,both acute and delayed | No information available |
| Endocrine Disruptor Information | No information available |
| Mobility | No information available |
![]() |
| Persistence and Degradability | Persistence is unlikely |
| Bioaccumulation/ Accumulation | |
| dicates whether each agency has listed any ingredient as acarcinogen | |
| Mutagenic Effects | No information available |
| Reproductive Effects | No information avai |
| Developmental Effects | No information available. |
| Teratogenicity | No information available. |
| Stot- single exposure | None known |

| Waste Disposal Methods |
Chemical waste generators must determine whether a discarded chemical is classifiedasahazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classificatio |

| DOT | |
| UN-No | UN1479 |
|
Proper Shipping Name |
Oxidizing solid, n.o.s. |
| Hazard Class | 5.1 |
| Packing Group | II |
| TDG | |
| UN-No | UN1479 |
| Proper Shipping Name | Oxidizing solid, n.o.s |
| Hazard Class | 5.1 |
| Packing Group | II |
| IATA | |
| UN-No | UN1479 |
| Proper Shipping Name | Oxidizing solid, n.o.s |
| Hazard Class | 5.1 |
| Packing Group | II |
| IMDG/IMO | |
| UN-No | UN1479 |
| Proper Shipping Name | Oxidizing solid, n.o.s |
| Hazard Class | 5.1 |
| Packing Group | II |

United States of America Inventory
| Component | CAS No | TSCA |
TSCA Inventory notification - Active-Inactive |
TSCA - EPA Regulatory Flags |
| Manganese(IV) oxide | 1313-13-9 | X | ACTIVE |
Legend
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
X - Listed '-' - Not Listed
TSCA 12(b) - Notices of Export Not applicable
| Component | CAS No | DSL | NDSL | EINECS | PICCS | ENCS | ISHL | AICS | KECL |
| Manganese oxide | 1313-13-9 | X |
|
215-202-6 | X | X | X | X | KE-23017 |

| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
| No data available |
| Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
