Part No: RXSOL-19-6245-012
Benzotriazole is popular Water Treatment Agent - As a corrosion inhibitor. Presence of Benzotriazole can delay the corrosion rate of copper.
Category
Benzotriazole is popular Water Treatment Agent - As a corrosion inhibitor. Presence of Benzotriazole can delay the corrosion rate of copper.
Benzotriazole is inexpensive and stable It behaves as an acid (pKa 8.2) and is highly soluble in basic solutions It is soluble in ethanol benzene toluene chloroform and DMF
Application
Benzotriazole Cas No.: 95-14-7
Benzotriazole (BTA) is a heterocyclic compound with the chemical formula C 6H 4N 3H. It can be viewed as the fusion of a benzene and triazole rings.
Safety Data (MSDS)
| Product Name | BENZOTRIAZOLE 75% |
| Part Number | RXSOL-19-6245-012 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
Substances
| Synonyms |
1,2,3-Benzotriazole
1H-Benzotriazole |
| Formula | C6H5N3 |
| Molecular weight | 119,12 g/mol |
| CAS-No. | 95-14-7 |
| EC-No. | 202-394-1 |
| Component | Classification | Concentration |
| 1H-Benzotriazole | ||
|
CAS-No. 95-14-7
EC-No 202-394-1
|
Acute Tox. 4; Eye Irrit. 2;
Aquatic Chronic 2; H302,
H319, H411
|
= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Classification according to Regulation (EC) No 1272/2008 |
Acute toxicity, Oral (Category 4), H302
Eye irritation (Category 2), H319
Long-term (chronic) aquatic hazard (Category 2), H411
For the full text of the H-Statements mentioned in this Section, see Section 16.
|
Label elements
| Signal Word | Warning |
|
Hazard Statements |
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
|
|
Precautionary Statements |
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (= 125 ml) | |
| Signal Word | Warning |
| Hazard statement(s) | None |
|
Precautionary
statement(s)
|
None |
|
Supplemental Hazard
Statements
|
None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
|
Description of first aid measures
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
Extinguishing media
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Carbon oxides
Nitrogen oxides (NOx)
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire
|
| Advice for firefighters |
In the event of fire, wear self-contained breathing apparatus. |
| Further information |
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
spray to keep fire-exposed containers cool.Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
|
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Environmental precautions | Do not let product enter drains. |
| Methods and materials for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
|
Conditions for safe storage, including any incompatibilities Storage conditions |
Tightly closed. Dry. |
| Storage class | Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Chloroprene
Minimum layer thickness: 0,65 mm
Break through time: 480 min
Material tested:KCL 720 Camapren®
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Latex gloves
Minimum layer thickness: 0,6 mm
Break through time: 60 min
Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M). |
| Body Protection | Flame retardant antistatic protective clothing. |
| Respiratory protection |
Recommended Filter type: Filter A-(P3)
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Powder |
| Colour | No data available |
| Odor | No data available |
| Melting point/freezing point | Melting point/range: 97 - 99 °C - lit. |
| Initial boiling point and boiling range | No data available |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits | No data available |
| Flash point | 170 °C - closed cup |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| pH |
No data available
materials.Extremely flammable in the presence of the following materials or conditions: oxidizing
materials.
|
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | 19 g/l at 25 °C - soluble |
| Partition coefficient: n-octanol/water | log Pow: 1,34 - Bioaccumulation is not expected. |
| Vapor pressure | No data available |
| Density | 1,36 g/cm3 at 20 °C |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | No data available |
| Reactivity |
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
The following applies in general to flammable organic substances and mixtures: in
correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
|
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions |
Violent reactions possible with:
Strong oxidizing agents
|
| Conditions to avoid |
Exposure to light may affect product quality.
Strong heating.
|
| Incompatible materials |
No data available
|
| Hazardous decomposition products | In the event of fire: see section 5 |
Information on toxicological effects
| Acute toxicity |
LD50 Oral - Rat - male and female - 500 mg/kg
(OECD Test Guideline 423)
LC50 Inhalation - Rat - 4 h - > 1,5 mg/l - dust/mist
Remarks: (RTECS)
LD50 Dermal - Rabbit - > 2.000 mg/kg
Remarks: (External MSDS)
|
| Skin corrosion/irritation |
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
|
| Serious eye damage/eye irritation |
Eyes - Rabbit
Result: Irritating to eyes. - 24 h
(OECD Test Guideline 405)
|
| Respiratory or skin sensitization |
Maximization Test - Guinea pig
Result: negative
(OECD Test Guideline 406)
|
| Germ cell mutagenicity |
Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Test Type: Micronucleus test
Species: Mouse
Method: OECD Test Guideline 474
Result: negative
|
| Carcinogenicity | No data available |
| Reproductive toxicity |
No data available
|
| Teratogenicity | No data available |
| Specific target organ toxicity (single exposure) | No data available |
| Specific target organ toxicity (repeated exposure) | No data available |
| Aspiration hazard | No data available |
| Additional information | |
|
Endocrine disrupting properties
Product
|
|
| Assessment |
The substance/mixture does not contain
components considered to have endocrine
disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU)
2018/605 at levels of 0.1% or higher.
RTECS: DM1225000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
Systemic effects:
After absorption:
Nausea
Vomiting
Cyanosis
Drowsiness
Dizziness
Diarrhea
Shortness of breath
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
|
| Toxicity | |
| Toxicity to fish | Semi-static test LC50 - Danio rerio (zebra fish) - 180 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | static test EC50 - Daphnia galeata (Water flea) - 8,58 mg/l - 48 h (OECD Test Guideline 202) |
| Toxicity to algae |
Growth inhibition ErC50 - Selenastrum capricornutum (green algae) -75 mg/l - 72 h
(OECD Test Guideline 201)
IC50 - Desmodesmus subspicatus (green algae) - 231 mg/l - 72 h
Remarks: (External MSDS)
|
| Toxicity to bacteria | EC50 - activated sludge - 1.060 mg/l (OECD Test Guideline 209) |
| Persistence and degradability | |
| Biodegradability |
Aerobic - Exposure time 28 d
Result: 0 % - Not readily biodegradable.
(OECD Test Guideline 301D)
|
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
|
Endocrine disrupting properties
Product
|
|
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available |
| Waste treatment Method | No data available |
| UN number | ADR/RID:3077 IMDG:3077 IATA: 3077 |
| UN proper shipping name |
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1HBenzotriazole)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1HBenzotriazole)
IATA: Environmentally hazardous substance, solid, n.o.s. (1H-Benzotriazole) |
| Transport hazard class(es) | ADR/RID: 9 IMDG: 9 IATA:9 |
| Packaging group | ADR/RID: IIl IMDG: lII IATA:IIl |
| Environmental hazards | ADR/RID: yes IMDG Marine pollutant: yes IATA: yes |
| Special precautions for user | No data available |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |